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Petroleum Processing

Zeolite Catalysts

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Zeolite Catalysts

One of the significant developments in FCC practice was the introduction of zeolite catalysts in 1965. Catalysts and additives play a major role in the selectivity and flexibility of FCC processes. FCC catalyst consists of a fine powder with an average particle size of 60–75 μm and a size distribution ranging from 20 to 120 μm. Four major components make up the catalysts: zeolite, active matrix, filler, and binder. Each of these constituents has a unique role to play, but zeolite is the key component that is more active and selective for high-octane number gasoline production [4]. Table 7.4 compares the octane numbers of some refinery products and FCC gasoline.

Components of FCC catalyst: binder, clay, pores, pseudocrystalline matrix systems, zeolite (60-70um)
Figure 7.9. Components of FCC catalyst [4].
Credit: Dr. Semih Eser © Penn State is licensed under CC BY-NC-SA 4.0

Table 7.4: Gasoline Octane Number

Product

RON

(600 rpm)

MON

(900 rpm)

Regular - Premium Gasoline 90-100 80-90
Straight Run Gasoline 60-68 60-68
FCC Gasoline (light) 93 82
FCC Gasoline (heavy) 95 85