In this module, you will learn about the devastating basaltic fissure eruption of Lakagígar (Laki Fissures), also known as the Skaftar Fires eruption, which took place between June 1783 and February 1784. The sequence of events and resulting destruction was recorded in great detail by Jón Steingrímsson, a priest in a nearby village who observed the eruption as it occurred. Much of what we know of the eruption and its aftermath comes from the writings of Steingrímsson and his contemporaries, combined with modern observations of the tephra deposits. Although Lakagígar was by no means a small eruption – it produced ~15 km3 of basaltic lava and tephra – what made the eruption particularly deadly was the large mass of volcanic gases and aerosols released into the atmosphere. Some of these aerosols remained in the upper atmosphere, reflecting the sun’s radiation and causing global mean temperatures to drop, while some fell out as acid rain, destroying crops and livestock. Most of the estimated 9,000 deaths in Iceland and as many as 20,000 worldwide that have been attributed to the eruption resulted from famine and disease, which were widespread across western Europe in 1784.
This said week, and the two prior to it, more poison fell from the sky than words can describe: ash, volcanic hairs, rain full of sulfur and salt peter, all of it mixed with sand. The snouts, nostrils, and feet of livestock grazing or walking on the grass turned bright yellow and raw. All water went tepid and light blue in color and gravel slides turned gray. All the earth's plants burned, withered and turned gray, one after the another, as the fire increased and neared the settlements.
- Rev. Jón Steingrímsson, Fires of the Earth, The Laki Eruption (1783-1784)
This module will take us one week to complete. Please refer to the Course Syllabus for specific time frames and due dates. Specific directions for the assignment below can be found within this module.
REQUIREMENTS | ASSIGNMENT DETAILS |
---|---|
TO DO | Review all the Module 2 Material. |
TO WATCH | BBC Volcano Live: Iceland Erupts [2] |
DISCUSSION | Add your post and comments to the Module 2 Discussion in Canvas |
QUIZ | Be sure to submit the Module 2 Quiz in Canvas |
LAB ASSIGNMENT | Mentos and Diet Coke / Volcano Degassing |
If you have any questions, please post them to our Questions? discussion forum (not e-mail) in Canvas. I will check that discussion forum daily to respond. While you are there, feel free to post your own responses if you, too, are able to help out a classmate.
Before proceeding to the description of events at Lakagígar, please watch this video about Icelandic volcanism featuring the great David Attenborough. The footage will give you a sense of what a fire fountain emerging from a fissure looks like up close.
Note: the description of events given below is taken from contemporary written accounts, summarized and translated from the Icelandic by Thordarson and Self (Bulletin of Volcanology, v. 55, p. 233-263, 1993).
Weak seismic tremors were first reported in the areas around Laki Mountain and the Skafta River in mid-May, 1783. The seismic activity grew in intensity over the next several weeks, until people were so unsettled by it that they took to sleeping in tents outside of their homes. The first fissure opened at 9 AM on June 8, 1783, producing fire fountains that were visible from the nearby towns of Skaftártunga, Medalland, and Sída. By reconstructing the line of sight from Prestbakki over Mörtunga, a ranch mentioned by name in Steingrímsson’s account, it can be determined that these first fire fountains were located near Hnúta, at the southwest end of the Laki fissures. Strong earthquakes were felt again on June 9-11, and were followed by more fire fountaining a bit farther to the north (contemporary accounts say the second fires were to the north – most likely they were actually to the northeast, following the trend of the fissure). The eruptions of June 8 and June 10 produced tephra deposits up to 60 cm thick extending to the north and east, and lava flows extending southwest towards the Skaftá River Gorge. Another earthquake swarm on June 13 preceded the rupture of a third fire fountain on June 14. This event produced a significant amount of Pele’s hair, which we learned about in Module 1 [3]. Lava flows from the June 14 fissure followed a somewhat more southerly path before joining with the flows still emerging from the June 8 and June 10 fissures at the Skaftá River Gorge. An earthquake on June 23 was followed two days later by explosive fountaining that peaked on June 27-28, raining ash and tephra on nearby towns. Interaction with the shallow water table resulted in a phreatomagmatic eruption, producing a large tuff cone centered on the fourth fissure. Lava flows emerging from the mouth of the Skaftá River Gorge were more or less continuous from June 12-29, with a surge following the opening of each new fissure. The fifth and most sustained explosive event on the Laki fissures occurred between June 30 and July 25, 1783. The initiation of this stage is not well documented, but it is known that earthquakes occurred on June 30, and tephra fell on local villages July 9-10. It is believed that all of the first five fissures were fountaining during this time. A lava surge—the last to be reported—emerged from the Skaftá River Gorge July 13-14. Tephra fall and seismic activity continued intermittently through July 25. The fissure that opened during this episode bisected the western flank of the older Laki hyaloclastite mountain, from which Lakagígar takes its name.
Eruptive activity northeast of Laki mountain commenced on July 29, 1783, marked by explosive phreatomagmatic activity. The phreatomagmatic eruption lasted 2-3 days, producing a second tuff cone. Lava flowed both to the south and to the north, ultimately entering the Hverfisfljót River Gorge to form a second flow channel that would drain the lavas produced by the northeast fissures. The lava flow rate reached a maximum of 4 km/day between August 3-7, continuing at a lower rate until the next surge on September 1 (preceded by an earthquake swarm on August 23). Another earthquake swarm on September 26 was accompanied by intense volcanic activity, and both the Skaftá and Hverfisfljót rivers dried up during this time. Another fissure opened October 24-29, delivering a final surge of lava to the Hverfisfljót River Gorge. Effusive eruption continued at a diminished rate until February 7, 1874.
Basaltic liquids are characterized by low viscosities and relatively low volatile contents, such that basaltic eruptions tend to be more effusive than explosions. However, this doesn’t mean that basaltic lavas always flow quietly from the Earth. Explosive basaltic eruptions and fire fountains can send volcanic tephra tens to hundreds of meters into the air – sometimes more than a kilometer! The table below explains the eruptive styles observed at Lakagígar; it is by no means exhaustive.
Two types of tephra are found today at Lakagígar, providing physical evidence of the styles of volcanism during the 1783-84 eruption. The two tephra types are classified by Thordarson and Self (1993) as strombolian and phreatomagmatic. The strombolian tephra is most common and is characterized by a glassy skin covering the surface of each clast (lapillus), indicating that it was still partially molten as it was falling. These lapilli in fact could be the products of either strombolian or hawaiian style volcanism. The phreatomagmatic tephra has no glassy skin and is entirely vesiculated, indicating that it was completely fragmented upon eruption.
Question - Multiple Choice
What style of volcanism is shown in the movie above?
Click for answer.
Iceland is unique in that it is the only place in the world where a mid-ocean ridge protrudes above sea level. Iceland straddles the Mid-Atlantic Ridge, with the North American Plate to the west and the Eurasian Plate to the east, and ~2 cm/yr relative motion in opposing directions. Much, although probably not all, of the magmatism at Iceland is a result of mantle decompression beneath this divergent plate boundary.
In Module 1, we learned that tectonic plates move across Earth’s surface relative to a more or less fixed reference frame of mantle plumes. So what are these plates, and why do they move? The Earth’s lithosphere – which consists of the crust and the rigid upper portion of the mantle – is broken up into 15 major plates, plus several micro-plates. The tectonic plates move with respect to one another – some moving apart at divergent boundaries, some coming together at convergent boundaries, and some sliding past each other at transform boundaries. The lithospheric plates ride on top of the flowing, plastic mantle asthenosphere.
The geothermal gradient inside the Earth is such that temperature increases with depth. The higher temperatures at the core-mantle boundary (~2,900 km depth) relative to the lithosphere-asthenosphere boundary (~100-200 km depth) drive convection in the plastic, flowing asthenosphere. This works very similarly to water convecting in a pot that’s being heated on the stove – hot fluid is less dense and therefore it rises, while the dense cooler fluid sinks. Just remember that the “fluid” in the mantle is actually a flowing solid; it is more viscous and flows much more slowly than water in a pot – at a rate of millimeters per year. Most geoscientists agree that there is a close relationship between mantle convection and plate tectonics, although it remains unclear to what extent the convecting mantle “drags” the lithospheric plates along its surface, or if instead the sinking of lithospheric plates at subduction zones serves to initiate convection cells in the mantle. In the most general sense, we can imagine that tectonic plates move away from each other at places where the mantle is rising, and together at places where the mantle is sinking.
New oceanic crust is more or less continuously being formed at mid-ocean ridges, which are a type of divergent plate boundary. It was mentioned above that the North American and Eurasian plates are moving away from each other at ~2 cm/yr at Iceland. As it turns out, this is a pretty representative average spreading rate for the Mid-Atlantic Ridge, which means that if you were to fly from John F. Kennedy International Airport in New York to London’s Heathrow Airport today, the trip would be 1 meter longer than if you had taken the same flight 50 years ago!
Question 1 - Short Answer
The central Pacific Ocean is spreading at a rate of ~5 cm/yr. How many years does it take for the distance between Mexico City and Hawaii to increase by 1 meter?
Click for answer.
Question 2 - Short Answer
Now let’s scale it up to geologic timescales. At a spreading rate of 5 cm/yr, how much would the distance between Hawaii and Mexico City increase in 100 million years? Give your answer in kilometers.
Click for answer.
Question 3 - Multiple Choice
How does this distance compare to the distance between New York and Los Angeles?
Click for answer.
In Module 1, we learned how the mantle sometimes melts as a result of a thermal anomaly (“hot spot”) that elevates the local geotherm above the mantle solidus. A close look at the diagonal orientation of the mantle solidus on a pressure-temperature diagram suggests that the mantle should also be able to melt under the influence of a pressure anomaly. That is, a rapid decrease in pressure can cause the mantle to melt, even without an increase in temperature. We call this kind of melting adiabatic – or, more commonly, decompression melting. Decompression melting commonly occurs at divergent plate boundaries, where two tectonic plates are moving away from each other. Mid-ocean ridges are the classic example, but adiabatic melting also occurs during continental lithospheric extension and in some mantle plumes.
According to the diagram above, at approximately what depth does adiabatic melting begin?
Click for answer.
Iceland is unique in that many researchers believe that a mantle plume is rising up through the Mid-Atlantic Ridge here. Thus melting at Iceland probably involves both high-temperature melting due to a thermal anomaly and decompression melting related to the divergent boundary. This may explain why eruption rates are so high (a significant eruption occurs once every 2-3 years), and why it is the only place on Earth where a mid-ocean ridge is exposed above sea level. The relative travel times of seismic waves beneath Iceland (seismic waves travel more slowly through hot or partially molten materials) have been used to map a narrow anomaly extending to at least 400 km depth, which many believe to be evidence of an Icelandic mantle plume. However, it is important to keep in mind that 400 km depth is still only the uppermost part of the asthenosphere, nowhere near the 2,900 km depth of the core-mantle boundary (which is generally believed to be the origin of hot mantle plumes). Some scientists believe that the plume does extend into the deep mantle, but cannot be imaged at depth because it is so narrow that it cannot be resolved using seismic imaging techniques.
The Skaftar Fires eruption was one of the five deadliest eruptions of the past 250 years. More than 9,000 people are estimated to have died within Iceland, nearly all due to starvation and disease in the months that followed the eruption itself. This accounts for ~20% of the population of Iceland at the time of the eruption, but the devastation was not limited to the island. Approximately 10,000-20,000 additional deaths across Europe in 1784 are attributed to respiratory ailments, a severe winter, and failed crops, which very likely were exacerbated by - if not entirely a result of - the Lakagígar eruption.
The Icelandic word móðuharðindin, meaning “mist hardships”, is used to describe the difficult times following the Lakagígar eruption. Acid rain destroyed crops and about three quarters of the island’s livestock. Animals that grazed on plants or drank from rivers contaminated with volcanic fluorine developed skeletal fluorosis, making it painful to eat or move. Sulfur is a minor component of the Earth’s mantle that tends to be concentrated in basaltic magmas. When basalt erupts as lava above the surface, the large pressure decrease allows the sulfur to be released in the form of sulfur dioxide (SO2) – the process is similar to the way carbon dioxide is released from a bottle of soda when you reduce the pressure by removing the lid. Scientists estimate that ~122 megatons of SO2 were released during the Lakagígar eruption. Upon combining with water in the atmosphere, this would have been converted to ~200 megatons of atmospheric aerosols, which were predominantly H2SO4. A little less than 20% of these aerosols are released from the lava flows and remain close to the surface as a local haze, while the remaining ~80% are carried up into the lower stratosphere by the eruption column (fire fountains and phreatomagmatic events) and transported over long distances by atmospheric circulation.
Of the total aerosols that were produced during the Lakagígar eruption, almost 90% would have fallen out as acid rain (mostly over Europe), with a little over 10% remaining in the upper atmosphere and circulating for several years. Aerosols in the upper atmosphere increase the Earth’s albedo (percent of the Sun’s energy that is reflected into space before reaching the surface), resulting in global cooling, usually on the order of ~1˚C, lasting for months or years. This effect is referred to as volcanic winter, and may last right through the summer growing season and into the next year. Coming on the heels of an unusually hot summer, the winter of 1784 was one of the coldest and longest winters on record in much of Europe and North America. Crop yield was extremely poor, and thousands of people died of starvation.
In addition to being a father of the American Revolution, Ambassador to France, First Postmaster General of the United States, Governor of Pennsylvania, and inventor of the lightning rod, Franklin stove, and bifocal glasses, Benjamin Franklin was also an amateur meteorologist and oceanographer. Franklin observed that the severely cold winter of 1784 was preceded by an unusual haze, and he was the first to suggest that atmospheric contamination from volcanic eruptions might reduce the intensity of the sun’s energy reaching the Earth, resulting in winter weather so cold as to pose a hazard to society. The theory excerpted below was originally written as a letter and subsequently presented at a reading in 1784. In the letter, Franklin suggests that the “dry fog” observed in Europe and North America may have originated from Hecla (sic). Hekla, an Icelandic volcano, erupted in 1766 and not again until 1845. The eruption Franklin is referring to in his letter is almost certainly that of Lakagígar.
METEOROLOGICAL IMAGINATIONS and CONJECTURES
by BENJAMIN FRANKLIN.
During several of the summer months of the year 1783, when the effect of the sun's rays to heat the earth in these northern regions should have been greater, there existed a constant fog over all Europe, and great part of North America. This fog was of a permanent nature; it was dry, and the rays of the sun seemed to have little effect towards dissipating it, as they easily do a moist fog, arising from water. They were indeed rendered so faint in passing through it, that when collected in the focus of a burning glass they would scarce kindle brown paper. Of course, their summer effect in heating the earth was exceedingly diminished. Hence the surface was early frozen; Hence the first snows remained on it unmelted, and received continual additions. Hence the air was more chilled, and the winds more severely cold.
Hence perhaps the winter of 1783-4, was more severe, than any that had happened for many years.
The cause of this universal fog is not yet ascertained. Whether it was adventitious to this earth, and merely a smoke, proceeding from the consumption by fire of some of those great burning balls or globes which we happen to meet with in our rapid course round the fun, and which are sometimes seen to kindle and be destroyed in passing our atmosphere, and whose smoke might be attracted and retained by our earth; or whether it was the vast quantity of smoke, long continuing to issue during the summer from Hecla in Iceland, and that other volcano which arose out of the sea near that island, which smoke might be spread by various winds, over the northern part of the world, is yet uncertain . It seems however worth the enquiry, whether other hard winters, recorded in history, were preceded by similar permanent and widely extended summer fogs. Because, if found to be so, men might from such fogs conjecture the probability of succeeding hard winter, and of the damage to be expected by the breaking up of frozen rivers in the spring; and take such measures as are possible and practicable, to secure themselves and effects from the mischiefs that attended the last.
Published in Memoirs of the Literary and Philosophical Society of Manchester, 1789, (pp. 373-377). T. Cadwell in the Strand: London.
In Part 1 of this lab activity, you will conduct the famous "Mentos and Diet Coke eruption", under more-or-less controlled experimental conditions. In Part 2, you will make some degassing calculations of your own. First, you will calculate the amount of CO2 released from a 2-liter bottle of Diet Coke. Then you will apply the same principles to calculate the amount of SO2 released during the 1783-84 eruption of Lakagígar.
This is going to be messy. I strongly recommend that you perform this experiment outside. If you can’t go outside, you can do it in the bathtub or shower using only one or two Mentos. You can also use soda water in place of Diet Coke. The fountain won’t be as high, but it will be easier to clean up! Make sure you have plenty of water on hand to rinse down the area after your experiment.
If you have someone to help you (or a trusty tripod), record a video of your eruption and turn it in! I’ll make a compilation of “greatest hits” for the website.
A bottle of soda contains dissolved carbon dioxide (CO2) under pressure. When you remove the lid, the pressure is released, and the CO2 exsolves in the form of tiny bubbles. When exsolution occurs faster than the gas can escape, the soda gets whipped up into a foam that quickly overflows the confined volume of the bottle – if you have ever shaken or dropped a bottle of soda before opening it, you have probably observed this effect yourself. In this experiment, the Mentos encourage the rapid formation of bubbles by providing a nucleation site. In the absence of a nucleation site, the CO2 gas must overcome the surface tension of the liquid before it can form a bubble, which inhibits the process a bit, especially at the beginning. Mint-flavored Mentos have a pitted surface with lots of surface area, which provides plenty of nucleation sites for bubble growth. The more Mentos, the more nucleation – hence, a soda eruption! It is less clear why Diet Coke works better than regular Coke, but based on observation this seems to be the case. Some people have suggested a chemical reaction involving the artificial sweeteners. However, any carbonated beverage will produce a fountain when Mentos are added, some will just be more dramatic than others. Incidentally, fruit-flavored Mentos do not produce an eruption. This is because they have a smooth waxy coating that does not provide nucleation sites for bubble formation.
Download the Excel Spreadsheet [7] to enter your experimental results
Download and complete the Worksheet for Lab 2: Degassing [8]
You will need to submit the results spreadsheet and the complete worksheet to the Module 2 Lab Assignment in Canvas.
The idea here is to determine the mass of CO2 you released into the atmosphere during the first part of your experiment. Watch your unit conversions!
First, a few assumptions:
We start by determining the total mass of CO2 present at the beginning of the experiment (prior to opening the bottle). In order to do this, first you will need to determine the mass of Diet Coke. Use the graph below to determine the density of water at 20˚C; we will assume your Diet Coke has the same density. Note that 1 cm3 = 1 mL.
Solubility is the amount of a compound that will remain in solution under a given set of conditions. Use the graph below to estimate the solubility of CO2 in water at 20˚C and atmospheric pressure.
The amount of CO2 released is given by the total amount present prior to opening the bottle minus the amount retained after the degassing experiment.
We can use the same approach to calculate the mass of SO2 released from the lava during the Lakagígar eruption. First, we need to estimate the mass of SO2 dissolved in the magma prior to eruption. But how does one determine the concentration of a volatile component prior to degassing, when all the lava and tephra samples we have are already degassed? The answer lies in tiny bits of glass trapped inside of crystals. We call these bits of glass melt inclusions, because they represent the magma that was present at the time the crystals formed. Once a melt inclusion has been overgrown by a crystal, the volatiles are trapped inside and cannot escape*.
The concentration of sulfur measured in melt inclusions from Lakagígar ranges from ~1200 to 1800 parts per million (ppm). We can use the best estimate of 1675 ppm from Thordarson et al., 1996. In order to convert this concentration into an equivalent mass of S, we need to multiply by the total mass of lava erupted. We can assume a best estimate of 15 km3 of lava erupted.
*In detail this is not entirely true – volatiles can still diffuse out through the solid crystals at high temperatures – but for the purposes of our calculations we can assume that they remain perfectly entrapped.
1. Assuming a basalt density of 2750 kg/m3, what is the total mass of lava erupted in megatons (109 kg)? Watch your units! Not only do you need to convert kilograms to megatons, but you also need to convert cubic kilometers to cubic meters.
Now multiply the mass of lava you just calculated by 1675/106 to get the mass of sulfur in the magma prior to degassing.
2. What is the total mass of sulfur before degassing?
Now, just as with the CO2 in Coke experiment, you will also need to estimate the mass of sulfur after degassing, which is determined by measuring the concentration of sulfur in the degassed tephra and lava. The best estimate given by Thordarson et al. is 205 ppm.
3. Using the same total mass of lava you used above, calculate the mass of sulfur remaining after degassing.
The difference between these two masses is the mass of sulfur released to the atmosphere.
4. What is the total mass of sulfur released to the atmosphere (in megatons)?
One last thing. The sulfur released to the atmosphere is not pure elemental sulfur, it is mostly in the form of SO2 gas. In order to convert the mass of S into the equivalent mass of SO2, you will need to multiply by the mass ratio of SO2 to S. You can use any periodic table (I like WebElements [11]) to calculate the molar mass of SO2. Then simply divide this by the molar mass of S, and you have the mass ratio. Multiply by the total mass of sulfur released, and you’re done!
5. What is the total mass of SO2 released to the atmosphere (in megatons)?
6. Thordarson et al. calculated 122.1 megatons of SO2 released. How close did your calculation come to theirs?
In Module 2, we learned about fissure eruptions by studying the 1783-84 eruption of Lakagígar in Iceland. Hopefully you noticed that although the type of lava erupted here - basalt - is the same type of lava erupted in Hawaii, the style of volcanism during this eruption was very different from what we typically see at Kilauea today. This basaltic fissure eruption produced fountains of lava that shot high into the air, and more importantly, emitted massive amouts of volatlie gases and aerosols into the atmosphere, with grave consequences for thousands of people living in the Northern Hemisphere. We also learned about mantle convection, mid-ocean ridges, and decompression melting. For our hands-on experiment this week, we created Diet Coke and Mentos "volcanoes" and used a little math to calculate gas emissions.
Congratulations! You have completed Module 2. Please return to the Assignments table on Page 1 to be sure you have completed all tasks.
If you have any questions, please post them to our Questions? discussion forum (not e-mail) in Canvas. I will check that discussion forum daily to respond. While you are there, feel free to post your own responses if you, too, are able to help out a classmate.
Links
[1] https://creativecommons.org/licenses/by/3.0/
[2] https://youtu.be/MlH7pCK4H-s
[3] http://dev.e-education.psu.edu/geosc30/node/666
[4] http://dev.e-education.psu.edu/geosc30/node/668
[5] https://commons.wikimedia.org/wiki/File%3ADiet_Coke_Mentos.jpg
[6] https://commons.wikimedia.org/wiki/File%3AShimadaK2007Sept09-MentosGeyser_DSC_3294%2B%2B.JPG
[7] https://www.e-education.psu.edu/rocco/sites/www.e-education.psu.edu.rocco/files/images/geosciences/Mentos_results.xlsx
[8] https://www.e-education.psu.edu/rocco/sites/www.e-education.psu.edu.rocco/files/Module%203%20Lab-corrected.docx
[9] http://www.chem1.com
[10] http://www.engineeringtoolbox.com/
[11] http://www.webelements.com