
By combining the transport processes outlined above, we can derive an expression for the mass conservation of a non-reactive solute as follows:
∂(ϕC)∂t=−∇⋅(Jadv+Jdisp)
Substitution of Eqn. (1) and (13) into Eqn. (16) yields
∂(ϕC)∂t=−∇⋅(ϕvC)+∇⋅(ϕDh∇C)
Equation (17) is the classical Advection-Dispersion equation (ADE). For one-dimensional systems, Equation (17) is simplified into
∂(ϕC)∂t=−∂(ϕvC)∂x+∂2(ϕDhC)∂x2
Analytical solution of ADE is available for homogeneous porous media [Zheng and Bennett, 2002]:
C=C02[erfc(L−vt2√Dht)+exp(vLDh)erfc(L+vt2√Dht)]
with the initial and boundary conditions:
C(x,0)=0x≥0C(0,t)=C0t≥0C(∞,t)=0t≥0
where C0 is the injecting concentration of the tracer, and erfc(B) is complementary error function:
erfc(B)=1−erf(B)=1−2√π∫B0e−t2dt∼1−√1−exp(−4B2π)
Here, erf(B) is error function, a special function of sigmoid shape that ocuurs in probability, statistics, and partial differential equations describing diffusion.