CE 574
Reactive transport in porous media

6.5 Advection Dispersion Equation (ADE)

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By combining the transport processes outlined above, we can derive an expression for the mass conservation of a non-reactive solute as follows:

(ϕC)t=(Jadv+Jdisp)

Substitution of Eqn. (1) and (13) into Eqn. (16) yields

(ϕC)t=(ϕvC)+(ϕDhC)

Equation (17) is the classical Advection-Dispersion equation (ADE). For one-dimensional systems, Equation (17) is simplified into

(ϕC)t=(ϕvC)x+2(ϕDhC)x2

Analytical solution of ADE is available for homogeneous porous media [Zheng and Bennett, 2002]:

C=C02[erfc(Lvt2Dht)+exp(vLDh)erfc(L+vt2Dht)]

with the initial and boundary conditions:

C(x,0)=0x0C(0,t)=C0t0C(,t)=0t0

where C0 is the injecting concentration of the tracer, and erfc(B) is complementary error function:

erfc(B)=1erf(B)=12πB0et2dt11exp(4B2π)
Here, erf(B) is error function, a special function of sigmoid shape that ocuurs in probability, statistics, and partial differential equations describing diffusion.