
ASTM Distillation (ASTM)
ASTM distillation also uses a batch operation, but in contrast to TBP, it operates without the presence of a contact plate and a reflux ratio (R/P, or RR) of zero, as shown in Figure 4.8a. There may be a slight unintentional reflux because of the condensation of the vapor on the tube that connects the flask to the condenser.

Figure 4.8a. ASTM distillation apparatus.
Credit: Dr. Semih Eser © Penn State is licensed under CC BY-NC-SA 4.0

Figure 4.8b. Distillation curve for ASTM distillation of the binary mixture A and B.
Credit: Dr. Semih Eser © Penn State is licensed under CC BY-NC-SA 4.0

Figure 4.8c. TBP distillation curve for distillation of the same binary mixture.
Credit: Dr. Semih Eser © Penn State is licensed under CC BY-NC-SA 4.0